Want to see your friends’ profile pictures when you chat with them.If yes, then you can do this through Gmail Setting .

Currently all Gmail profile chat photo are disable ,User have to Enable that feature to see Friend picture in Chat ,To to enable that Go to Gmail setting (Top right hand side) Select Lab tab and mark Enable picture in Chat .
If you have not uploaded yours Picture in Gmail profile then you can add that also either using Gtalk or via Google /Gmail setting .

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i want to add picture of my friends in chat with me on Gmail (Gtalk)